Hamiltonian paths (no tractable solution for this is known, yet the very similar Eulerian path, which is often presented as the seven bridges problem, has an easy tractable solution)
Longest path (this is interesting because finding the longest path is intractable, yet finding the shortest path is tractable - the shortest path is calculated when a GPS device works out the shortest route to a destination.
Also, a Hamiltonian problem can be reduced easily to longest path, showing the concept of reduction when one NP-complete problem is used to solve another).
Here's a song about it!